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Beilstein J. Org. Chem. 2013, 9, 2625–2628, doi:10.3762/bjoc.9.297
Graphical Abstract
Scheme 1: Gold(I)-catalyzed carbocyclization.
Scheme 2: Proposed mechanism for the gold(I)-catalyzed cyclization.
Scheme 3: Gold-catalyzed 5-exo-dig carbocyclization cascade.
Figure 1: Structure of senaequidolide (13) and ellipticine (14).
Beilstein J. Org. Chem. 2011, 7, 1007–1013, doi:10.3762/bjoc.7.114
Figure 1: Structures of naturally occurring PPAPs.
Scheme 1: Gold(I)-catalyzed 6-endo-dig cyclization.
Scheme 2: Synthesis of papuaforin A core 4.
Scheme 3: Proposed domino Diels–Alder reaction/gold(I)-catalyzed cyclization.
Scheme 4: One-pot Diels–Alder cycloaddition/gold(I) catalyzed carbocyclization.